Monday, December 15, 2014

Welding failure by stress corrosion cracking

A schematic diagram of a welded elbow pipe illustrated in Figure 3(a) is failed pipe that located at first stage superheater tubes in the boiler. It had been moderately cold-bent during installation. Non-destructive testing result shows the longitudinal cracking was located on the welding heat affected zone, along the weld beads (Figure 3b). The failure occurred after only 3 months of operation. The steam drum lacked adequate devices for separation of steam and water, and load swings were frequent, possibly causing carryover of boiler water. Microstructural analysis revealed plastically deformed grains from the cold bending. The cracks were highly branched and ran between the grains (intergranular) as they passed through the tube wall. The corrodent contains a slight sodium chloride from boiler-water carryover. The tube was then removed and sends to your consultancy firm for further failure investigation.

Figure 3: Schematic diagram of  (a) welded elbow pipe & (b) the cracking heat affected zone along the weld bead
(i)                 Give hypothesis the root cause of this pipe failure.
(ii)               Justify your hypothesis.
(iii)      If metallographic analysis performed on the failed area, determine the characteristics of the microstructure that will be observed under optical microscope.
(iv)             Recommend a few possible solutions to prevent the occurrence of this defect in the future?

Answer
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(i)                 Give hypothesis the root cause of this pipe failure.
            The root cause of failure is hypothesized as Stress Corrosion Cracking

(ii)               Justify your hypothesis.
            Generally welding contains internal stress.
            “Moderately cold-bent during installation” results residual/ internal stress”
            “The steam drum lacked adequate devices for separation of steam and water, and load        swings were frequent, possibly causing carryover of boiler water” results hot water          enter the tube & forces the acceleration of oxidation reaction
           “Micro structural analysis revealed plastically deformed grains from the cold bending”    shows an elongated grain proves the presents of residual/internal stress 
           “The cracks were highly branched” shows the presents of stress ran between the grains  (intergranular)” shows the presents of corrosion
           “The corrodent was consist of small content of sodium chloride from boiler-water  carryover” shows chloride ion from NaOH acts as active corrosion agent
          


(iii)      If metallographic analysis performed on the failed area, determine the characteristics of the microstructure that will be observed under optical microscope.

Schematic diagram of optical metallograph for SCC shows hairline, branching, Intergranular & Transgranular cracking


(iv)             Recommend a few possible solutions to prevent the occurrence of this defect in the future?
Stress corrosion cracking (SCC) requires three conditions to occur simultaneously,
      (a) a susceptible alloy,
      (b) tensile stresses, and
      (c) a specific corrosive environment.
For instance, the necessary tensile stress can be either externally applied or existing in the material due to forming or welding. If one condition is eliminated, SCC will not occur.

Prevention can be achieved by:
- Reducing the overall stress level and designing out stress concentrations
- Selection of a suitable material not susceptible to the environment
- Design to minimise thermal and residual stresses
- Developing compressive stresses in the surface the material
- Use of a suitable protective coating


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